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Organometallic chemistry


Kevin Burges Texas A&M University

Intramolecular dehydrogenative C-H Insertion reactions


not long ago DeBoef, Pastine and Sames reported the ring closure reaction shown in Reaction 1 (J Am Chem Soc 2004 126 6556) Moderate yields of the ring-closed a whole s 1 were obtained along with minor amounts of a 5,6-ring fused isomer (not shown) The character of the norbornene in the combination of parts to form a whole was to remove hydrogen by the agency of formation of norbornane.


fresh N-substituted carbene complexes

The catalyst used in Reaction 1 features the now widely used IPr ligand. In a new Science ...


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