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Film formation from surfactant-free, slightly crosslinked, Fluorescein-labeled polystyrene particles.

A steady state-fluorescence (SSF) technique for studying film formation from surfactant-free, slightly crosslinked polystyrene (PS) latex particles is reported. The dust films were prepared from fluorescein (F)-labeled P particles at range temperature. The mechanically strong films were obtained by the agency of annealing these films at elevated temperatures in 5 10 20 and 30 min time intervals above the glass transition ([Tsubg]) temperature of polystyrene Scattered light ([I.sub.s]) and fluorescence ([I.sub.F]) intensities from F were monitored after each annealing pace to investigate the three different film formation stages called void closure healing, and interdiffusion. The evolution of transparency of the latex films was


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